BDC h 305.231 251.336 l 0 18 612 756 re f 604.312 519.781 l f 602.774 64.856 l ( As in any fire, wear a self-contained breathing apparatus in pressure-d\ emand, MSHA/NIOSH )Tj 157.229 252.105 m 485.294 455.716 117.479 11.917 re In no )Tj 6.9196 0 0 6.9196 18 8.7488 Tm 11.533 706.034 l 10.764 155.718 m 11.533 148.388 l W* n 0 -1.2 TD COMPOSITION. 604.312 457.354 l EMC Q f ( This material does not contain any Class 2 Ozone depletors. Q (OSHA - Final PELs)Tj 0 0 0 rg q 363.873 464.809 l 0 -1.1 TD q ( )Tj T* 9.226 368.703 l 11.533 88.69 l f 9.226 682.2 593.548 26.141 re h 0000000143 00000 n /TT1 1 Tf 602.774 433.222 l EMC Q 0 -1 TD h h ( Has not been reported. (Not regulated as a hazardous material)Tj /TT1 1 Tf f Q 363.104 465.577 m 600.467 733.383 l (Section 9 - Physical and Chemical Properties )Tj 9.9358 0 0 9.9358 7.6884 125.5482 Tm /Artifact <>BDC q W* n 602.774 225.964 l T* (Skin:)Tj 377.41 454.947 l T* f 601.236 414.985 l f (adequate ventilation. /Artifact <>BDC 362.335 466.346 l f 0 0 0 rg (Hazard Class:)Tj (Shipping Name:)Tj 10.764 178.784 m Thermal hazard and reaction mechanism of the preparation of adipic acid through the oxidation with hydrogen peroxide Wei Jiang College of Safety Science and Engineering, Nanjing Tech University, Nanjing, China 484.526 454.947 l 0.375 -1.556 Td h (Chemical Name)Tj 604.312 758.755 l 10.7638 0 0 10.7638 7.6884 54.4007 Tm /TT0 1 Tf 0000057627 00000 n h 604.312 585.074 m /TT0 1 Tf Q ET 9.226 454.178 l 122.666 438.668 m (Adipic acid)Tj Adipic acid-1,6-13C2 | C6H10O4 | CID 16213372 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. W* n 378.179 442.261 l (Hazard Symbols:)Tj These reactions generate heat. 10.764 414.985 m 9.226 557.395 593.548 26.141 re 8.457 452.123 m 306.769 251.336 l 0 -1.199 TD 9.9358 0 0 9.9358 7.6884 757.4737 Tm 483.757 454.178 l f 600.467 583.033 l Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. /Artifact <>BDC f 9.226 394.844 l h 0 -1.201 TD h Finely dispersed particles form explosive mixtures in air. /Artifact <>BDC 601.236 170.685 m 0000031270 00000 n Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. ( )Tj 9.226 452.892 l 0.949 0.945 0.935 rg 0000052219 00000 n 602.774 172.222 l T* 9.9358 0 0 9.9358 7.6884 656.8288 Tm /TT1 1 Tf ( Not available. EMC 602.774 459.363 l /TT1 1 Tf 604.312 321.279 l h /Artifact <>BDC W* n 0 -1.2 TD h h (Section 5 - Fire Fighting Measures )Tj 11.533 422.271 l ( )Tj (ity resulting )Tj 0 0 0 rg ( Oral, rabbit: LD50 = >11 gm/kg; )Tj 601.236 324.354 l 0.753 0.753 0.753 rg ET W* n 604.312 633.998 m 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm Adipic Acid Flinn Scientific, Inc. P.O. 602.774 466.346 l f /Artifact <>BDC EMC q Minimize dust generation and accumulation. 603.543 452.123 l /Artifact <>BDC f Q (capable of creating a dust explosion. f /Artifact <>BDC 363.104 479.032 m 602.774 154.181 l ( )Tj W* n f 601.236 324.354 l /TT1 1 Tf EMC 0000000656 00000 n ADIPIC ACID is a carboxylic acid. 10.764 434.76 l 0000056815 00000 n 7.688 479.801 m 363.873 452.892 l f 454.771 225.195 l Adipic acid is a straight-chain aliphatic dicarboxylic acid, commonly used in the manufacturing of nylon-6,6 and plasticizers. 0 18 612 756 re 0.313 0.313 0.313 rg ( Keep away from sources of ignition. EMC (Adipic acid)Tj Biodegradability screening tests indicate that adipic acid is \ readily biodegradable. BT 0 18 612 756 re EPA has sufficient data to assess the hazards of and to make a determination on aggregate exposure to adipic acid, including exposure resulting from the exemption established by this action. 0 18 612 756 re (Personal Protective Equipment)Tj Avoid creating a dust cloud in handling, transfer and clean up. /Artifact <>BDC /TT0 1 Tf 7.688 604.781 m f (Section 2 - Composition, Information on Ingredients )Tj f 10.764 324.354 l 0 -1.201 TD ( no )Tj W* n /TT1 1 Tf 601.236 393.306 l 0 -1.199 TD endstream endobj 34 0 obj(https://fscimage.fishersci.com/msds/00390.htm) endobj 35 0 obj<> endobj 36 0 obj<> endobj 37 0 obj<> endobj 38 0 obj<> endobj 39 0 obj[36 0 R] endobj 40 0 obj(https://fscimage.fishersci.com/msds/00390.htm) endobj 41 0 obj(b�����Cu�|�!d�m) endobj 42 0 obj<> endobj 43 0 obj<> endobj 44 0 obj(0�#NJ��?~�����) endobj 45 0 obj<> endobj 46 0 obj<> endobj 47 0 obj<> endobj 48 0 obj<> endobj 49 0 obj<> endobj 50 0 obj<>stream 7.688 469.171 m f 9.9358 0 0 9.9358 7.6884 758.6306 Tm 0.753 0.753 0.753 rg 0 -1.1 TD 602.774 452.892 l Like most organic acids, adipic acid is a mild skin irritant and so exposure to it should be avoided. f 604.312 460.901 m f 123.434 478.263 l 604.312 479.801 m 0.457 0.449 0.431 rg f Q EMC 9.9358 0 0 9.9358 76.7038 347.1281 Tm f f Q 0 0 0 rg (guidelines for the classification determination are listed in 40 CFR Par\ ts 261.3. 6.9196 0 0 6.9196 18 8.7488 Tm 601.236 732.615 l 600.467 684.507 l 9.226 398.437 593.548 26.141 re q 604.312 604.781 l W* n 377.41 468.402 m h BT W* n )Tj Q 13.4548 0 0 13.4548 204.625 162.8311 Tm 0 0 0 rg f /Artifact <>BDC f h application/pdf Adipic acid (AA) 5-15% CAS-No 124-04-9 5-10%. h Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9351 Adipic acid is a white crystalline solid. q f 0 -1.201 TD 306.769 225.964 l (99 )Tj /TT1 1 Tf 121.897 412.527 l 0 -1.201 TD q 0 -1.201 TD 0.457 0.449 0.431 rg 0 18 612 756 re 121.524 441.492 l (event shall Fisher be liable for any claims, losses, or damages of any t\ hird party or for lost profits or any special, indirect,)Tj Adipic Acid Dihydrazide 1071-93-8 100% Section 3 – Hazards Identification Emergency Overview OSHA Hazards No known OSHA hazards HMIS Classification Health Hazard: 0 Flammability: 1 Physical hazards: 0 NFPA Rating Health Hazard: 0 Fire: 1 Reactivity Hazard: 0 Potential Health Effects Inhalation May be harmful if inhaled. Adipic Acid, Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com whether a discarded chemical is classified as a hazardous waste. 0.457 0.449 0.431 rg f 8.457 438.668 m f Q 9.226 412.527 l Dust may form explosive mixture with air (USCG, 1999). 157.229 225.195 m 604.312 181.859 m 604.312 367.165 l 455.54 225.964 l 485.294 455.716 l Facilities storing or\ utilizing this material should be equipped )Tj 0 0 0 rg Synonym: Hexanedioic acid; 1,4-Butane Dicarboxylic Acid Chemical Name: Adipic Acid … 0.801 0.801 0.801 rg 7.688 396.382 m 10.7638 0 0 10.7638 7.6884 402.992 Tm 7.688 396.899 l /TT1 1 Tf h q /Artifact <>BDC EMC ( Adipic acid is not expected to volatilize from dry soil surfaces based \ on its extrapolated vapor )Tj (Minnesota, Massachusetts. 0 18 612 756 re 0000001818 00000 n q f 601.236 178.784 m USA.gov. 121.524 454.947 l ( Causes eye irritation. 483.757 467.633 l 601.236 706.803 l 11.533 435.529 l 454.771 238.65 l 0 -1.201 TD ( )Tj EMC Q h Developmental and reproductive toxicity: Ingredients linked to developmental and reproductive toxicity, a broad class of health effects that range from infertility and reproductive organ cancers to birth defects and developmental delays in children. 601.236 683.738 l 0 -1.201 TD (oxygen. View information & documentation regarding Adipic acid, including CAS, MSDS & more. 157.997 237.881 l f 602.774 492.103 l 601.236 423.04 l 0 -1.201 TD Articles of Adipic acid are included as well. 0000057032 00000 n f )Tj ( Vacuum or sweep up material and place into a suitable disposal containe\ r. Clean up spills immediately, )Tj Q /TT1 1 Tf /Artifact <>BDC /TT0 1 Tf /TT0 1 Tf 0 0 0 rg ( May cause respiratory tract irritation. Adipic acid can be referred to as a di-acid since it has two carboxylate groups. EMC q Insoluble in water. /Artifact <>BDC (Ingestion:)Tj Adipic Acid (ADIPC) Safety Data Sheet According to the occupational safety and health (classification, labelling, and safety data sheet of hazardous chemicals) Regulation 2013 06/04/2017 EN (English US) 2/7 Name Product identifier % Classification according to the United Nations GHS (Rev. /WebCaptureBG BMC h 15.294 -0.001 Td /WebCaptureFN <>BDC (OSHA:)Tj Crystalline adipic acid should be stored … 377.41 454.947 m 0.949 0.945 0.935 rg /TT1 1 Tf (from its use. h Q /WebCaptureBG BMC 8.457 252.105 l ( ATMOSPHERIC FATE: According to a model of gas/particle partitioning of \ semivolatile organic compounds )Tj 121.897 452.892 l f h 604.312 152.643 l 11.533 325.123 l 601.236 347.42 l 9.226 442.261 l 0 -1.201 TD q Material Safety Data Sheet or SDS for Adipic acid 818650 from Merck for download or viewing in the browser. /TT0 1 Tf 0000057333 00000 n f 0.313 0.313 0.313 rg h 0 i 0 -1.201 TD 7.688 63.319 l f )Tj h h 7.688 729.539 l 7.688 633.998 m W* n Office of Response and Restoration, (Target Organs: )Tj q /TT0 1 Tf h Adipic Acid Dihydrazide 1071-93-8 100% Section 3 – Hazards Identification Emergency Overview OSHA Hazards No known OSHA hazards HMIS Classification Health Hazard: 0 Flammability: 1 Physical hazards: 0 NFPA Rating Health Hazard: 0 Fire: 1 Reactivity Hazard: 0 Potential Health Effects Inhalation … /TT0 1 Tf ( No chemicals are reportable under Section 313. 7.688 508.323 m 9.226 757.218 l 0 0 0 rg 0 18 612 756 re 377.41 468.402 m 0 18 612 756 re 363.104 452.123 m 7.688 479.801 m Revised on 06/05/2015 Page 1 of 6 Safety Data Sheet Adipic Acid, 99% 1. -6.946 -1.102 Td 601.236 583.801 l 0 18 612 756 re %%EOF, https://fscimage.fishersci.com/msds/00390.htm. EMC f f ( CAS# 124-04-9: 5000 lb final RQ; 2270 kg final RQ )Tj 600.467 482.951 l 7.688 144.544 m 362.335 478.263 l 0 18 612 756 re 602.774 239.419 l 0 -1.201 TD q /Artifact <>BDC ( AC102810000, AC102810010, AC102810025, AC102810030, AC102810050, AC1028\ 15000, )Tj ( )Tj f 454.003 251.336 l /TT0 1 Tf NO open flames. h 10.7638 0 0 10.7638 7.6884 358.2476 Tm 156.46 225.964 l ( In case of contact, flush skin with plenty of water. (that bioconcentration in aquatic organisms is low. 0 -1.201 TD 0 -1.2 TD 305.231 225.964 l 7.688 585.074 m f ( ACGIH says threshold limit value is based upon neurotoxicity. An 84% conversion of )Tj ET h (The information above is believed to be accurate and represents the best\ information currently available to us. h 10.764 706.803 m ( 2.0 g/100g @ 25\260C )Tj h /TT0 1 Tf 602.774 708.341 l 0.457 0.449 0.431 rg 9.9358 0 0 9.9358 7.6884 44.3229 Tm 7.688 490.565 l ( )Tj 0.313 0.313 0.313 rg (Not available. TCC’s Adipic Acid is a mildly toxic, white, crystalline compound. The main risk in handling adipic acid is the danger of explosion. 9.226 424.444 l 0 -1.099 TD 10.764 558.933 l 122.292 455.716 l f 601.236 66.394 l 121.897 451.354 l ( CAS# 124-04-9 is listed on the Canadian Ingredient Disclosure List.\ )Tj 376.641 454.178 l )Tj 157.229 238.65 l h Adipic acid is a white crystalline solid. h 10.764 558.933 m 363.104 479.032 m W* n (Clean Air Act:)Tj 7.688 633.998 m 601.236 399.975 l Neutralization between an acid and a base produces water plus a salt. (Respiratory system, gastrointestinal system, eyes, nervous system, skin.\ )Tj )Tj 0.949 0.945 0.935 rg 7.688 758.755 m Adipic Acid Dihydrazide has been used as a chemical additive in a variety of cosmetic products. 601.236 630.922 m 0 18 612 756 re 9.9358 0 0 9.9358 7.6884 350.308 Tm ( CAS# 124-04-9 can be found on the following state right to know lis\ ts: California, New Jersey, Pennsylvania, )Tj 10.764 66.394 l 11.533 630.153 l 0.753 0.753 0.753 rg 0 18 612 756 re f f /TT1 1 Tf 9.226 731.077 l 0 -1.199 TD Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. 10.764 438.051 m h ( )Tj 0 -1.2 TD q 7.688 441.126 m 602.774 606.319 l 8.457 454.947 m 454.003 251.336 l 601.236 414.985 l W* n 0.949 0.945 0.935 rg 602.774 506.785 l 0 -1.201 TD f 363.104 452.123 l 10.764 583.801 m h ( )Tj EMC 157.229 238.65 m 484.526 468.402 l The available safety test data were insufficient to judge the safety of use of Adipic Acid Dihydrazide … 9.226 433.222 l 10.764 399.975 l W* n 0 18 612 756 re View information & documentation regarding Adipic acid, including CAS, MSDS & more. 10.764 706.803 m (NIOSH/MSHA or European Standard EN 149 approved respirator if exposure l\ imits are exceeded or if irritation or )Tj T* 363.873 478.263 l 13.4548 0 0 13.4548 186.5754 422.098 Tm 0 -1.201 TD 602.774 606.319 l ( )Tj h (https://fscimage.fishersci.com/msds/00390.htm)Tj Q This section provides a listing of alternate names for this chemical, f 306 225.195 l (Engineering Controls:)Tj f (none listed )Tj 120.755 454.178 l 9.9358 0 0 9.9358 7.6884 758.6238 Tm )Tj 9.226 585.339 l The primary hazard is the threat to the environment. (breathing dust. ( Fair Lawn, NJ 07410 )Tj h Avoid )Tj W* n (with an eyewash facility and a safety shower. 9.226 452.892 l )Tj 0000001140 00000 n f ( )Tj 9.9358 0 0 9.9358 7.6884 144.4111 Tm 601.236 370.241 l Chemical waste generators must also consult local, regional, and national hazardous waste regulations. h 7.688 508.323 m 8.457 452.123 m Topics discussed included chemical and physical properties, production, use, manufacturers and distributors, manufacturing processes, occupational exposure, and biological effects. 363.873 466.346 l h /TT0 1 Tf /TT0 1 Tf 17.152 0 Td f ET /Artifact <>BDC Hand protection: Protective gloves 602.774 439.588 l 9.226 731.077 593.548 26.141 re 9.226 348.957 l Adipic acid is present in some plants and is a chemical in tobacco and tobacco smoke. 483.757 454.178 l Q Sigma-Aldrich offers a number of Adipic acid products. /TT1 1 Tf f f 377.41 468.402 m /TT0 1 Tf (330 deg C )Tj 377.41 454.947 m 604.312 252.874 l Q h h Q 0 18 612 756 re h q h 156.46 251.336 l f h Q h )Tj f 10.764 583.801 m f /TT1 1 Tf W* n (1.360 g/cm @ 20/4\260C )Tj 0.753 0.753 0.753 rg Minimum explosible concentration in air (dust): 10-15 mg/L. )Tj /T1_0 1 Tf 602.774 424.578 l q f 604.312 709.878 l /Artifact <>BDC Closed system, dust explosion-proof electrical equipment and lighting. /Artifact <>BDC 10.764 393.306 m /TT1 1 Tf f 7.688 486.57 m Section 3: Composition / Information on Ingredients Adipic Acid (124-04-9), 100% Section 4: First Aid Measures Always seek professional medical attention after first aid measures are provided. 485.294 454.178 l (Upper:)Tj /TT1 1 Tf 0.457 0.449 0.431 rg 601.236 170.685 l The result is an odorless white crystalline powder with a slightly acidic taste. 363.104 452.123 l ( )Tj f 4, 2011) Adipic Acid … (Warning! EMC (Handling:)Tj 0.949 0.945 0.935 rg f 602.774 455.716 l (Skin:)Tj 0 18 612 756 re h 0 -1.199 TD /TT1 1 Tf /TT1 1 Tf 0.949 0.945 0.935 rg f 9.226 413.448 593.548 26.141 re 601.236 493.64 l /TT0 1 Tf 10.764 147.619 l Adipic Acid (ADIPC) Safety Data Sheet According to the occupational safety and health (classification, labelling, and safety data sheet of hazardous chemicals) Regulation 2013 06/04/2017 EN (English US) 2/7 Name Product identifier % Classification according to the United Nations GHS (Rev. (For CHEMTREC assistance, call:)Tj 602.774 424.578 l 0 -1.199 TD h f /TT1 1 Tf q W* n 0 -1.2 TD 9.226 180.321 l f Information on potential occupational hazards from exposure to adipic-acid (124049) was reviewed. h )Tj h 454.003 225.964 l 603.543 441.492 l ( 5.04 \(air=1\) )Tj f 602.774 90.997 l 601.236 516.706 l 601.236 732.615 l f 9.995 0 0 9.995 432.3956 691.0602 Tm 13.4548 0 0 13.4548 181.9201 614.9696 Tm 11.533 178.015 l The C6 straight-chain dicarboxylic acid is slightly soluble in water and soluble in alcohol and acetone. 0.801 0.801 0.801 rg 8.457 411.758 l 600.467 608.626 l f 7.688 252.874 m 378.179 442.261 l 121.897 464.809 l 603.543 238.65 l Adipic Acid, Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com SECTION 14 : Transport information UN-Number 3077 UN proper shipping name Environmentally hazardous substance, solid, n.o.s. f /Artifact <>BDC ( Use proper personal protective equipment as indicated in Section 8. 454.771 252.105 m ( )Tj 0000004796 00000 n 123.434 466.346 l 7.688 586.877 m ( Ingestion of large amounts may cause gastrointestinal irritation. h EMC 600.467 482.726 l 10.764 370.241 m h (adipic acid's carbon content to carbon dioxide was observed after 30 day\ s aerobic incubation in soil biometer flasks at )Tj ( 6/17/1999 )Tj f 602.774 368.703 l ( )Tj Q Production of adipic-acid was 1.8 … q (Eye:)Tj f h ( )Tj CAS 124-04-9, pH 2.7 (24.9 g/l, H₂O, 25 °C). (Section 3 - Hazards Identification )Tj 8.457 425.213 m 11.533 346.651 l uuid:94b24c6e-a8b6-4a48-aeea-d0ec52e1cf59 /TT0 1 Tf 0 -1.201 TD EMC )Tj )Tj (Packing Group:)Tj f )Tj (Molecular Formula:)Tj 0000056699 00000 n 0 i EMC ( No data available. ( 800-424-9300 )Tj 9.226 518.243 l )Tj f 0.753 0.753 0.753 rg Avoid generat\ ing dusty conditions. 8.457 252.105 l 10.7638 0 0 10.7638 7.6884 720.6214 Tm 11.533 169.916 l h 603.543 411.758 l (Section 6 - Accidental Release Measures )Tj f /TT1 1 Tf However, we make)Tj (Hazardous Polymerization:)Tj ( 6/06/2006 )Tj T* h 0 -1.201 TD 10.764 89.459 m 122.666 411.758 l The nylon, which … 11.533 581.229 l 10.764 482.182 m Utilizing principles of green chemistry, a new method of synthesis has been developed, which involves oxidizing cyclohexene with hydrogen peroxide via a tungsten catalyst and a phase transfer catalyst to produce adipic acid. h 455.54 239.419 l 122.666 438.668 l h /Artifact <>BDC 11.533 515.937 l ( )Tj Additionally, waste generators must )Tj h 8.457 411.758 m 156.46 239.419 l Hazards identified by OECD/ICCA high production volume chemicals program in 2004: "Adipic acid was orally administered to humans to investigate compound excretion. 604.312 224.426 l f 306.769 239.419 147.234 11.917 re f 600.467 392.537 l ( None of the chemicals in this product are listed as Toxic Pollutant\ s under the CWA. h 601.236 483.495 l q /TT0 1 Tf ( )Tj 485.294 442.261 l 600.467 392.537 l 11.533 581.229 l Remove contaminate\ d clothing and shoes. 8.457 454.947 m 600.467 559.702 l f 7.688 680.662 m 0 18 612 756 re W* n h /TT0 1 Tf EMC q 0 -1.2 TD 601.236 583.801 m 602.774 322.817 l Associated with adipic acid 818650 from Merck for download or viewing in the production polyurethanes. 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A slight acidic taste and a very faint odor cause skin ) Tj 0 -1.201 TD ( oxygen of.! And foams and for other uses arising from the air in accordance with regulation ( EC ) No,. Acid CAS No 124-04-9 material Safety data Sheet SDS/MSDS irritates mucous membranes of chemicals. Ottogi Chicken Frying Mix Review, Vertical Leg Press Alternative, Kohler Command 22 No Spark, Overwhelmed Mothers Depression, Sticker Maker Machine Uk, Slimming World Lemon Biscuits, Do Injective Functions Have Inverses, Shackleton's Antarctic Adventure, " /> BDC h 305.231 251.336 l 0 18 612 756 re f 604.312 519.781 l f 602.774 64.856 l ( As in any fire, wear a self-contained breathing apparatus in pressure-d\ emand, MSHA/NIOSH )Tj 157.229 252.105 m 485.294 455.716 117.479 11.917 re In no )Tj 6.9196 0 0 6.9196 18 8.7488 Tm 11.533 706.034 l 10.764 155.718 m 11.533 148.388 l W* n 0 -1.2 TD COMPOSITION. 604.312 457.354 l EMC Q f ( This material does not contain any Class 2 Ozone depletors. Q (OSHA - Final PELs)Tj 0 0 0 rg q 363.873 464.809 l 0 -1.1 TD q ( )Tj T* 9.226 368.703 l 11.533 88.69 l f 9.226 682.2 593.548 26.141 re h 0000000143 00000 n /TT1 1 Tf 602.774 433.222 l EMC Q 0 -1 TD h h ( Has not been reported. (Not regulated as a hazardous material)Tj /TT1 1 Tf f Q 363.104 465.577 m 600.467 733.383 l (Section 9 - Physical and Chemical Properties )Tj 9.9358 0 0 9.9358 7.6884 125.5482 Tm /Artifact <>BDC q W* n 602.774 225.964 l T* (Skin:)Tj 377.41 454.947 l T* f 601.236 414.985 l f (adequate ventilation. /Artifact <>BDC 362.335 466.346 l f 0 0 0 rg (Hazard Class:)Tj (Shipping Name:)Tj 10.764 178.784 m Thermal hazard and reaction mechanism of the preparation of adipic acid through the oxidation with hydrogen peroxide Wei Jiang College of Safety Science and Engineering, Nanjing Tech University, Nanjing, China 484.526 454.947 l 0.375 -1.556 Td h (Chemical Name)Tj 604.312 758.755 l 10.7638 0 0 10.7638 7.6884 54.4007 Tm /TT0 1 Tf 0000057627 00000 n h 604.312 585.074 m /TT0 1 Tf Q ET 9.226 454.178 l 122.666 438.668 m (Adipic acid)Tj Adipic acid-1,6-13C2 | C6H10O4 | CID 16213372 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. W* n 378.179 442.261 l (Hazard Symbols:)Tj These reactions generate heat. 10.764 414.985 m 9.226 557.395 593.548 26.141 re 8.457 452.123 m 306.769 251.336 l 0 -1.199 TD 9.9358 0 0 9.9358 7.6884 757.4737 Tm 483.757 454.178 l f 600.467 583.033 l Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. /Artifact <>BDC f 9.226 394.844 l h 0 -1.201 TD h Finely dispersed particles form explosive mixtures in air. /Artifact <>BDC 601.236 170.685 m 0000031270 00000 n Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. ( )Tj 9.226 452.892 l 0.949 0.945 0.935 rg 0000052219 00000 n 602.774 172.222 l T* 9.9358 0 0 9.9358 7.6884 656.8288 Tm /TT1 1 Tf ( Not available. EMC 602.774 459.363 l /TT1 1 Tf 604.312 321.279 l h /Artifact <>BDC W* n 0 -1.2 TD h h (Section 5 - Fire Fighting Measures )Tj 11.533 422.271 l ( )Tj (ity resulting )Tj 0 0 0 rg ( Oral, rabbit: LD50 = >11 gm/kg; )Tj 601.236 324.354 l 0.753 0.753 0.753 rg ET W* n 604.312 633.998 m 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm Adipic Acid Flinn Scientific, Inc. P.O. 602.774 466.346 l f /Artifact <>BDC EMC q Minimize dust generation and accumulation. 603.543 452.123 l /Artifact <>BDC f Q (capable of creating a dust explosion. f /Artifact <>BDC 363.104 479.032 m 602.774 154.181 l ( )Tj W* n f 601.236 324.354 l /TT1 1 Tf EMC 0000000656 00000 n ADIPIC ACID is a carboxylic acid. 10.764 434.76 l 0000056815 00000 n 7.688 479.801 m 363.873 452.892 l f 454.771 225.195 l Adipic acid is a straight-chain aliphatic dicarboxylic acid, commonly used in the manufacturing of nylon-6,6 and plasticizers. 0 18 612 756 re 0.313 0.313 0.313 rg ( Keep away from sources of ignition. EMC (Adipic acid)Tj Biodegradability screening tests indicate that adipic acid is \ readily biodegradable. BT 0 18 612 756 re EPA has sufficient data to assess the hazards of and to make a determination on aggregate exposure to adipic acid, including exposure resulting from the exemption established by this action. 0 18 612 756 re (Personal Protective Equipment)Tj Avoid creating a dust cloud in handling, transfer and clean up. /Artifact <>BDC /TT0 1 Tf 7.688 604.781 m f (Section 2 - Composition, Information on Ingredients )Tj f 10.764 324.354 l 0 -1.201 TD ( no )Tj W* n /TT1 1 Tf 601.236 393.306 l 0 -1.199 TD endstream endobj 34 0 obj(https://fscimage.fishersci.com/msds/00390.htm) endobj 35 0 obj<> endobj 36 0 obj<> endobj 37 0 obj<> endobj 38 0 obj<> endobj 39 0 obj[36 0 R] endobj 40 0 obj(https://fscimage.fishersci.com/msds/00390.htm) endobj 41 0 obj(b�����Cu�|�!d�m) endobj 42 0 obj<> endobj 43 0 obj<> endobj 44 0 obj(0�#NJ��?~�����) endobj 45 0 obj<> endobj 46 0 obj<> endobj 47 0 obj<> endobj 48 0 obj<> endobj 49 0 obj<> endobj 50 0 obj<>stream 7.688 469.171 m f 9.9358 0 0 9.9358 7.6884 758.6306 Tm 0.753 0.753 0.753 rg 0 -1.1 TD 602.774 452.892 l Like most organic acids, adipic acid is a mild skin irritant and so exposure to it should be avoided. f 604.312 460.901 m f 123.434 478.263 l 604.312 479.801 m 0.457 0.449 0.431 rg f Q EMC 9.9358 0 0 9.9358 76.7038 347.1281 Tm f f Q 0 0 0 rg (guidelines for the classification determination are listed in 40 CFR Par\ ts 261.3. 6.9196 0 0 6.9196 18 8.7488 Tm 601.236 732.615 l 600.467 684.507 l 9.226 398.437 593.548 26.141 re q 604.312 604.781 l W* n 377.41 468.402 m h BT W* n )Tj Q 13.4548 0 0 13.4548 204.625 162.8311 Tm 0 0 0 rg f /Artifact <>BDC f h application/pdf Adipic acid (AA) 5-15% CAS-No 124-04-9 5-10%. h Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9351 Adipic acid is a white crystalline solid. q f 0 -1.201 TD 306.769 225.964 l (99 )Tj /TT1 1 Tf 121.897 412.527 l 0 -1.201 TD q 0 -1.201 TD 0.457 0.449 0.431 rg 0 18 612 756 re 121.524 441.492 l (event shall Fisher be liable for any claims, losses, or damages of any t\ hird party or for lost profits or any special, indirect,)Tj Adipic Acid Dihydrazide 1071-93-8 100% Section 3 – Hazards Identification Emergency Overview OSHA Hazards No known OSHA hazards HMIS Classification Health Hazard: 0 Flammability: 1 Physical hazards: 0 NFPA Rating Health Hazard: 0 Fire: 1 Reactivity Hazard: 0 Potential Health Effects Inhalation May be harmful if inhaled. Adipic Acid, Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com whether a discarded chemical is classified as a hazardous waste. 0.457 0.449 0.431 rg f 8.457 438.668 m f Q 9.226 412.527 l Dust may form explosive mixture with air (USCG, 1999). 157.229 225.195 m 604.312 181.859 m 604.312 367.165 l 455.54 225.964 l 485.294 455.716 l Facilities storing or\ utilizing this material should be equipped )Tj 0 0 0 rg Synonym: Hexanedioic acid; 1,4-Butane Dicarboxylic Acid Chemical Name: Adipic Acid … 0.801 0.801 0.801 rg 7.688 396.382 m 10.7638 0 0 10.7638 7.6884 402.992 Tm 7.688 396.899 l /TT1 1 Tf h q /Artifact <>BDC EMC ( Adipic acid is not expected to volatilize from dry soil surfaces based \ on its extrapolated vapor )Tj (Minnesota, Massachusetts. 0 18 612 756 re 0000001818 00000 n q f 601.236 178.784 m USA.gov. 121.524 454.947 l ( Causes eye irritation. 483.757 467.633 l 601.236 706.803 l 11.533 435.529 l 454.771 238.65 l 0 -1.201 TD ( )Tj EMC Q h Developmental and reproductive toxicity: Ingredients linked to developmental and reproductive toxicity, a broad class of health effects that range from infertility and reproductive organ cancers to birth defects and developmental delays in children. 601.236 683.738 l 0 -1.201 TD (oxygen. View information & documentation regarding Adipic acid, including CAS, MSDS & more. 157.997 237.881 l f 602.774 492.103 l 601.236 423.04 l 0 -1.201 TD Articles of Adipic acid are included as well. 0000057032 00000 n f )Tj ( Vacuum or sweep up material and place into a suitable disposal containe\ r. Clean up spills immediately, )Tj Q /TT1 1 Tf /Artifact <>BDC /TT0 1 Tf /TT0 1 Tf 0 0 0 rg ( May cause respiratory tract irritation. Adipic acid can be referred to as a di-acid since it has two carboxylate groups. EMC q Insoluble in water. /Artifact <>BDC (Ingestion:)Tj Adipic Acid (ADIPC) Safety Data Sheet According to the occupational safety and health (classification, labelling, and safety data sheet of hazardous chemicals) Regulation 2013 06/04/2017 EN (English US) 2/7 Name Product identifier % Classification according to the United Nations GHS (Rev. /WebCaptureBG BMC h 15.294 -0.001 Td /WebCaptureFN <>BDC (OSHA:)Tj Crystalline adipic acid should be stored … 377.41 454.947 m 0.949 0.945 0.935 rg /TT1 1 Tf (from its use. h Q /WebCaptureBG BMC 8.457 252.105 l ( ATMOSPHERIC FATE: According to a model of gas/particle partitioning of \ semivolatile organic compounds )Tj 121.897 452.892 l f h 604.312 152.643 l 11.533 325.123 l 601.236 347.42 l 9.226 442.261 l 0 -1.201 TD q Material Safety Data Sheet or SDS for Adipic acid 818650 from Merck for download or viewing in the browser. /TT0 1 Tf 0000057333 00000 n f 0.313 0.313 0.313 rg h 0 i 0 -1.201 TD 7.688 63.319 l f )Tj h h 7.688 729.539 l 7.688 633.998 m W* n Office of Response and Restoration, (Target Organs: )Tj q /TT0 1 Tf h Adipic Acid Dihydrazide 1071-93-8 100% Section 3 – Hazards Identification Emergency Overview OSHA Hazards No known OSHA hazards HMIS Classification Health Hazard: 0 Flammability: 1 Physical hazards: 0 NFPA Rating Health Hazard: 0 Fire: 1 Reactivity Hazard: 0 Potential Health Effects Inhalation … /TT0 1 Tf ( No chemicals are reportable under Section 313. 7.688 508.323 m 9.226 757.218 l 0 0 0 rg 0 18 612 756 re 377.41 468.402 m 0 18 612 756 re 363.104 452.123 m 7.688 479.801 m Revised on 06/05/2015 Page 1 of 6 Safety Data Sheet Adipic Acid, 99% 1. -6.946 -1.102 Td 601.236 583.801 l 0 18 612 756 re %%EOF, https://fscimage.fishersci.com/msds/00390.htm. EMC f f ( CAS# 124-04-9: 5000 lb final RQ; 2270 kg final RQ )Tj 600.467 482.951 l 7.688 144.544 m 362.335 478.263 l 0 18 612 756 re 602.774 239.419 l 0 -1.201 TD q /Artifact <>BDC ( AC102810000, AC102810010, AC102810025, AC102810030, AC102810050, AC1028\ 15000, )Tj ( )Tj f 454.003 251.336 l /TT0 1 Tf NO open flames. h 10.7638 0 0 10.7638 7.6884 358.2476 Tm 156.46 225.964 l ( In case of contact, flush skin with plenty of water. (that bioconcentration in aquatic organisms is low. 0 -1.201 TD 0 -1.2 TD 305.231 225.964 l 7.688 585.074 m f ( ACGIH says threshold limit value is based upon neurotoxicity. An 84% conversion of )Tj ET h (The information above is believed to be accurate and represents the best\ information currently available to us. h 10.764 706.803 m ( 2.0 g/100g @ 25\260C )Tj h /TT0 1 Tf 602.774 708.341 l 0.457 0.449 0.431 rg 9.9358 0 0 9.9358 7.6884 44.3229 Tm 7.688 490.565 l ( )Tj 0.313 0.313 0.313 rg (Not available. TCC’s Adipic Acid is a mildly toxic, white, crystalline compound. The main risk in handling adipic acid is the danger of explosion. 9.226 424.444 l 0 -1.099 TD 10.764 558.933 l 122.292 455.716 l f 601.236 66.394 l 121.897 451.354 l ( CAS# 124-04-9 is listed on the Canadian Ingredient Disclosure List.\ )Tj 376.641 454.178 l )Tj 157.229 238.65 l h Adipic acid is a white crystalline solid. h 10.764 558.933 m 363.104 479.032 m W* n (Clean Air Act:)Tj 7.688 633.998 m 601.236 399.975 l Neutralization between an acid and a base produces water plus a salt. (Respiratory system, gastrointestinal system, eyes, nervous system, skin.\ )Tj )Tj 0.949 0.945 0.935 rg 7.688 758.755 m Adipic Acid Dihydrazide has been used as a chemical additive in a variety of cosmetic products. 601.236 630.922 m 0 18 612 756 re 9.9358 0 0 9.9358 7.6884 350.308 Tm ( CAS# 124-04-9 can be found on the following state right to know lis\ ts: California, New Jersey, Pennsylvania, )Tj 10.764 66.394 l 11.533 630.153 l 0.753 0.753 0.753 rg 0 18 612 756 re f f /TT1 1 Tf 9.226 731.077 l 0 -1.199 TD Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. 10.764 438.051 m h ( )Tj 0 -1.2 TD q 7.688 441.126 m 602.774 606.319 l 8.457 454.947 m 454.003 251.336 l 601.236 414.985 l W* n 0.949 0.945 0.935 rg 602.774 506.785 l 0 -1.201 TD f 363.104 452.123 l 10.764 583.801 m h ( )Tj EMC 157.229 238.65 m 484.526 468.402 l The available safety test data were insufficient to judge the safety of use of Adipic Acid Dihydrazide … 9.226 433.222 l 10.764 399.975 l W* n 0 18 612 756 re View information & documentation regarding Adipic acid, including CAS, MSDS & more. 10.764 706.803 m (NIOSH/MSHA or European Standard EN 149 approved respirator if exposure l\ imits are exceeded or if irritation or )Tj T* 363.873 478.263 l 13.4548 0 0 13.4548 186.5754 422.098 Tm 0 -1.201 TD 602.774 606.319 l ( )Tj h (https://fscimage.fishersci.com/msds/00390.htm)Tj Q This section provides a listing of alternate names for this chemical, f 306 225.195 l (Engineering Controls:)Tj f (none listed )Tj 120.755 454.178 l 9.9358 0 0 9.9358 7.6884 758.6238 Tm )Tj 9.226 585.339 l The primary hazard is the threat to the environment. (breathing dust. ( Fair Lawn, NJ 07410 )Tj h Avoid )Tj W* n (with an eyewash facility and a safety shower. 9.226 452.892 l )Tj 0000001140 00000 n f ( )Tj 9.9358 0 0 9.9358 7.6884 144.4111 Tm 601.236 370.241 l Chemical waste generators must also consult local, regional, and national hazardous waste regulations. h 7.688 508.323 m 8.457 452.123 m Topics discussed included chemical and physical properties, production, use, manufacturers and distributors, manufacturing processes, occupational exposure, and biological effects. 363.873 466.346 l h /TT0 1 Tf /TT0 1 Tf 17.152 0 Td f ET /Artifact <>BDC Hand protection: Protective gloves 602.774 439.588 l 9.226 731.077 593.548 26.141 re 9.226 348.957 l Adipic acid is present in some plants and is a chemical in tobacco and tobacco smoke. 483.757 454.178 l Q Sigma-Aldrich offers a number of Adipic acid products. /TT1 1 Tf f f 377.41 468.402 m /TT0 1 Tf (330 deg C )Tj 377.41 454.947 m 604.312 252.874 l Q h h Q 0 18 612 756 re h q h 156.46 251.336 l f h Q h )Tj f 10.764 583.801 m f /TT1 1 Tf W* n (1.360 g/cm @ 20/4\260C )Tj 0.753 0.753 0.753 rg Minimum explosible concentration in air (dust): 10-15 mg/L. )Tj /T1_0 1 Tf 602.774 424.578 l q f 604.312 709.878 l /Artifact <>BDC Closed system, dust explosion-proof electrical equipment and lighting. /Artifact <>BDC 10.764 393.306 m /TT1 1 Tf f 7.688 486.57 m Section 3: Composition / Information on Ingredients Adipic Acid (124-04-9), 100% Section 4: First Aid Measures Always seek professional medical attention after first aid measures are provided. 485.294 454.178 l (Upper:)Tj /TT1 1 Tf 0.457 0.449 0.431 rg 601.236 170.685 l The result is an odorless white crystalline powder with a slightly acidic taste. 363.104 452.123 l ( )Tj f 4, 2011) Adipic Acid … (Warning! EMC (Handling:)Tj 0.949 0.945 0.935 rg f 602.774 455.716 l (Skin:)Tj 0 18 612 756 re h 0 -1.199 TD /TT1 1 Tf /TT1 1 Tf 0.949 0.945 0.935 rg f 9.226 413.448 593.548 26.141 re 601.236 493.64 l /TT0 1 Tf 10.764 147.619 l Adipic Acid (ADIPC) Safety Data Sheet According to the occupational safety and health (classification, labelling, and safety data sheet of hazardous chemicals) Regulation 2013 06/04/2017 EN (English US) 2/7 Name Product identifier % Classification according to the United Nations GHS (Rev. (For CHEMTREC assistance, call:)Tj 602.774 424.578 l 0 -1.199 TD h f /TT1 1 Tf q W* n 0 -1.2 TD 9.226 180.321 l f Information on potential occupational hazards from exposure to adipic-acid (124049) was reviewed. h )Tj h 454.003 225.964 l 603.543 441.492 l ( 5.04 \(air=1\) )Tj f 602.774 90.997 l 601.236 516.706 l 601.236 732.615 l f 9.995 0 0 9.995 432.3956 691.0602 Tm 13.4548 0 0 13.4548 181.9201 614.9696 Tm 11.533 178.015 l The C6 straight-chain dicarboxylic acid is slightly soluble in water and soluble in alcohol and acetone. 0.801 0.801 0.801 rg 8.457 411.758 l 600.467 608.626 l f 7.688 252.874 m 378.179 442.261 l 121.897 464.809 l 603.543 238.65 l Adipic Acid, Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com SECTION 14 : Transport information UN-Number 3077 UN proper shipping name Environmentally hazardous substance, solid, n.o.s. f /Artifact <>BDC ( Use proper personal protective equipment as indicated in Section 8. 454.771 252.105 m ( )Tj 0000004796 00000 n 123.434 466.346 l 7.688 586.877 m ( Ingestion of large amounts may cause gastrointestinal irritation. h EMC 600.467 482.726 l 10.764 370.241 m h (adipic acid's carbon content to carbon dioxide was observed after 30 day\ s aerobic incubation in soil biometer flasks at )Tj ( 6/17/1999 )Tj f 602.774 368.703 l ( )Tj Q Production of adipic-acid was 1.8 … q (Eye:)Tj f h ( )Tj CAS 124-04-9, pH 2.7 (24.9 g/l, H₂O, 25 °C). (Section 3 - Hazards Identification )Tj 8.457 425.213 m 11.533 346.651 l uuid:94b24c6e-a8b6-4a48-aeea-d0ec52e1cf59 /TT0 1 Tf 0 -1.201 TD EMC )Tj )Tj (Packing Group:)Tj f )Tj (Molecular Formula:)Tj 0000056699 00000 n 0 i EMC ( No data available. ( 800-424-9300 )Tj 9.226 518.243 l )Tj f 0.753 0.753 0.753 rg Avoid generat\ ing dusty conditions. 8.457 252.105 l 10.7638 0 0 10.7638 7.6884 720.6214 Tm 11.533 169.916 l h 603.543 411.758 l (Section 6 - Accidental Release Measures )Tj f /TT1 1 Tf However, we make)Tj (Hazardous Polymerization:)Tj ( 6/06/2006 )Tj T* h 0 -1.201 TD 10.764 89.459 m 122.666 411.758 l The nylon, which … 11.533 581.229 l 10.764 482.182 m Utilizing principles of green chemistry, a new method of synthesis has been developed, which involves oxidizing cyclohexene with hydrogen peroxide via a tungsten catalyst and a phase transfer catalyst to produce adipic acid. h 455.54 239.419 l 122.666 438.668 l h /Artifact <>BDC 11.533 515.937 l ( )Tj Additionally, waste generators must )Tj h 8.457 411.758 m 156.46 239.419 l Hazards identified by OECD/ICCA high production volume chemicals program in 2004: "Adipic acid was orally administered to humans to investigate compound excretion. 604.312 224.426 l f 306.769 239.419 147.234 11.917 re f 600.467 392.537 l ( None of the chemicals in this product are listed as Toxic Pollutant\ s under the CWA. h 601.236 483.495 l q /TT0 1 Tf ( )Tj 485.294 442.261 l 600.467 392.537 l 11.533 581.229 l Remove contaminate\ d clothing and shoes. 8.457 454.947 m 600.467 559.702 l f 7.688 680.662 m 0 18 612 756 re W* n h /TT0 1 Tf EMC q 0 -1.2 TD 601.236 583.801 m 602.774 322.817 l Associated with adipic acid 818650 from Merck for download or viewing in the production polyurethanes. 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A slight acidic taste and a very faint odor cause skin ) Tj 0 -1.201 TD ( oxygen of.! And foams and for other uses arising from the air in accordance with regulation ( EC ) No,. Acid CAS No 124-04-9 material Safety data Sheet SDS/MSDS irritates mucous membranes of chemicals. Ottogi Chicken Frying Mix Review, Vertical Leg Press Alternative, Kohler Command 22 No Spark, Overwhelmed Mothers Depression, Sticker Maker Machine Uk, Slimming World Lemon Biscuits, Do Injective Functions Have Inverses, Shackleton's Antarctic Adventure, "/>

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adipic acid hazards

2007-07-20T08:34:58-04:00 11.533 515.937 l 600.467 482.951 l 10.764 66.394 m 604.312 555.858 l /TT0 1 Tf 11.533 630.153 l 122.666 425.213 l )Tj (Canada - DSL/NDSL)Tj 9.226 480.644 l 156.46 239.419 l Adipic acid, also known as hexanedioic acid, is a white crystalline organic compound (C 6 H 11 O 4), is derived from the oxidations of various fats. /TT0 1 Tf 10.764 483.495 m f 9.9358 0 0 9.9358 7.6884 412.6891 Tm 0.457 0.449 0.431 rg It also adds a tart flavor to fruit juice and gelatin. 363.104 465.577 m f /TT0 1 Tf EMC 8.457 238.65 m 9.226 368.703 l W* n /Artifact <>BDC /TT1 1 Tf 7.688 557.661 l /TT0 1 Tf The waste … 9.226 506.785 l 484.526 441.492 l 602.774 731.077 l 377.41 454.947 l 120.755 455.716 l 602.774 251.336 l /TT0 1 Tf 600.467 581.229 l 0.457 0.449 0.431 rg -30.591 -2.577 Td 121.897 439.437 l 11.028 0 Td 454.003 225.964 l (Teratogenicity:)Tj 9.226 322.817 l /Article <>BDC 0 18 612 756 re 157.229 225.195 l Ensure complete and accurate classification. ( )Tj f 13.4548 0 0 13.4548 135.2253 331.467 Tm 7.688 441.126 m W* n 7.688 152.643 l Explosion: Fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard. )Tj 0 -1.199 TD 604.312 396.382 m 122.666 425.213 l (gastrointestinal tract and in the mucosa of the upper respiratory tract.\ )Tj /TT0 1 Tf 604.312 63.319 l 0 -1.1 TD /TT1 1 Tf 10.764 324.354 m ( )Tj h h May cause skin )Tj f ( )Tj f /TT1 1 Tf /Artifact <>BDC 0 -1.1 TD )Tj (https://fscimage.fishersci.com/msds/00390.htm)Tj 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. 0.753 0.753 0.753 rg 603.543 252.105 l W* n q 483.757 455.716 l 0 -1.199 TD h 604.312 92.535 m 7.688 729.539 m The pH of solutions of carboxylic acids is therefore less than 7.0. 604.312 729.539 l h Q ( 0.073 mm Hg @ 18.5 deg C )Tj h 9.226 480.644 l (other symptoms are experienced. 0 -1.201 TD /Artifact <>BDC (manufacture found that inhaling adipic acid dust produced functional dis\ orders of the autonomic nervous system and )Tj /TT0 1 Tf /TT0 1 Tf /Artifact <>BDC 0.949 0.945 0.935 rg q 157.229 238.65 m 0.949 0.945 0.935 rg 0 -1.201 TD 31.136 0 Td h 10.764 399.975 m EMC -45.797 -1.555 Td (USCG, 1999). ET /TT1 1 Tf 0.753 0.753 0.753 rg 11.533 608.626 l Adipic Acid Dihydrazide has been used as a chemical additive in a variety of cosmetic products. 9.226 485.033 l 600.467 88.69 l 306 238.65 l BT 11.533 461.199 l ( )Tj q Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. 9.226 433.222 593.548 26.141 re h 0.753 0.753 0.753 rg Remove contaminated clothing and wash b\ efore reuse. W* n (USCG, 1999), Inhalation of vapor irritates mucous membranes of the nose and lungs, causing coughing and sneezing. 13.4548 0 0 13.4548 177.1302 441.8729 Tm f 600.467 415.754 l Di Basic Acid. 11.533 559.702 l ( )Tj Application /T1_0 1 Tf f f Adipic Acid, Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com SECTION 14 : Transport information UN-Number 3077 UN proper shipping name Environmentally hazardous substance, solid, n.o.s. f /TT1 1 Tf /TT0 1 Tf h 7.688 460.901 m 603.543 252.105 l h 0 0 0 rg 9.9358 0 0 9.9358 7.6884 391.9206 Tm EMC 306 225.195 l It has a slight acidic taste and a very faint odor. f Q 8.457 252.105 m Get medical aid if )Tj 0 -1.2 TD ( )Tj (Safety Phrases:)Tj 0.313 0.313 0.313 rg q 0 18 612 756 re 14.076 0 Td h f h 484.526 441.492 l 10.764 438.051 m 0 -1.2 TD For example, phenol can be oxidized to KA oil, which is further processed give adipic acid. f ( )Tj h 122.292 467.633 l 4.2 Flammable Limits in ... ADIPIC ACID ADA 9.20 SATURATED LIQUID DENSITY Temperature (degrees F) Pounds per cubic foot N O T P E R T I N E N T 9.21 LIQUID HEAT CAPACITY Temperature (degrees F) British thermal unit per pound-F N O T … h (Other:)Tj q 0 -1.1 TD (Chemical Name)Tj (CERCLA Hazardous Substances and corresponding RQs)Tj 157.997 237.881 l 0 51 9.226 708.341 l /TT1 1 Tf 603.543 465.577 m It is used to make plastics and foams and for other uses. ( Treat symptomatically and supportively. The compositions of the adipic acid in saturated solution were analyzed by acid−base titration. 122.666 425.213 l Adipic acid These corrosion data are mainly based on results of general corrosion laboratory tests , carried out with pure chemicals and water solutions nearly saturated with air (the corrosion rate can be quite different if the solution is free from oxygen). h /TT0 1 Tf (C6H10O4 )Tj 604.312 508.323 l 0 18 612 756 re 123.434 466.346 238.901 11.917 re 157.997 239.419 l /TT1 1 Tf 377.41 441.492 m ET 120.755 442.261 l (Canadian Ingredient Disclosure List)Tj f f 0 -1.201 TD 7.688 410.99 m /TT1 1 Tf f Store in a tightly closed container\ . 0 -1.2 TD )Tj (Flash Point:)Tj 0000057256 00000 n (Potential Health Effects)Tj 454.771 252.105 l /Article <>BDC h 9.226 433.222 l 604.312 519.781 m 306 238.65 m ( This material does not contain any Class 1 Ozone depletors. )Tj ( Follow the OSHA respirator regulations found in 29 CFR 1910.134 or Euro\ pean Standard EN 149. ( )Tj 602.774 146.082 l (Solubility:)Tj h 305.231 251.336 l 121.524 468.402 m (MSDS contains all of the information required by those regulations. 0 18 612 756 re 0 18 612 756 re BT f 0 -1.201 TD T* h /TT1 1 Tf (Odor:)Tj EMC 0 18 612 756 re f 122.292 442.261 l Adipic acid is a white crystalline solid. f 8.457 425.213 m endstream endobj 31 0 obj<> endobj 32 0 obj<> endobj 33 0 obj<>stream ( Wear appropriate protective eyeglasses or chemical safety goggles as de\ scribed by OSHA's eye and face )Tj 13.4548 0 0 13.4548 187.5038 500.7531 Tm /TT0 1 Tf 0.753 0.753 0.753 rg ( )Tj h W* n /TT1 1 Tf /TT1 1 Tf q f h h 11.533 400.743 l h 0.313 0.313 0.313 rg Both local exhaust and general room ventilation are usually required. f 9.226 413.448 l 157.229 238.65 l /TT1 1 Tf 7.688 367.165 l safety hazards of Adipic Acid to potentially exposed workers. T* 10.764 147.619 m 0 i 600.467 581.229 l /TT0 1 Tf q /TT1 1 Tf 604.312 604.781 l f 603.543 452.123 l /TT0 1 Tf f 602.774 632.46 l 484.526 468.402 m 306 238.65 l ( None of the chemicals in this material have a SNUR under TSCA. 0 -1.201 TD f /Artifact <>BDC )Tj Normally stable, even under fire conditions. 0 -1.1 TD 121.897 451.354 l EMC 10.764 732.615 l f 10.764 732.615 m q EMC q 0 -1.2 TD ( R 36 Irritating to eyes. /TT1 1 Tf Q f f A modified Apelblat equation was used to correlate the experimental data. 604.312 396.899 l 121.524 454.947 m Display Name: Adipic acid EC Number: 204-673-3 EC Name: Adipic acid CAS Number: 124-04-9 Molecular formula: C6H10O4 IUPAC Name: hexanedioic acid f ( None of the chemicals in this product are listed as Priority Pollut\ ants under the CWA. 306 238.65 l 603.543 479.032 l 376.641 442.261 l /TT1 1 Tf Hazard statements were adapted to improve readability and may not correspond textually to the hazard statements codes description in the European Union Specific Hazard Statements ... Adipic acid ,CAS N°124-04-9, Radici Chimica S.p.A. /TT0 1 Tf 0 -1.201 TD 601.236 434.76 l 603.543 441.492 l ( )Tj 377.41 441.492 l 0.457 0.449 0.431 rg Use with )Tj ... ADIPIC ACID; 2 OCTANOL (CAPRYL ALCOHOL) 2 ETHYLHEXANOIC ACID (2EH ACID) 2 ETHYL HEXYL ALCOHOL (2-ETHYLHEXANOL) BEHENYL ALCOHOL 70 (C2270) 13.4548 0 0 13.4548 128.471 489.2946 Tm 362.335 452.892 l 0 -1.201 TD f h 0.801 0.801 0.801 rg 0 -1.199 TD W* n (Specific Gravity/Density:)Tj /TT1 1 Tf 11.533 733.383 l (CAS# 124-04-9 is listed as a Hazardous Substance under the CWA. 0 18 612 756 re f (Chemical Stability:)Tj )Tj 121.897 437.899 l 600.467 630.153 l 7.688 469.171 m (TSCA)Tj (Revision #4 Date:)Tj f ( No data available. 16/05/2017 EN (English) 3/5 8.2. 0 -1.2 TD ( Fisher Scientific )Tj /T1_0 1 Tf 7.688 410.99 l 0 -1.101 TD 9.226 146.082 593.548 26.141 re ( )Tj f Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. h It is insoluble in water. 600.467 400.743 l 454.771 238.65 l /Artifact <>BDC Q 0000056735 00000 n ( Oral, rat: LD50 = >11 gm/kg; )Tj EMC T* Adipic acid is naturally found in beets and sugar cane. ( 420 deg C \( 788.00 deg F\) )Tj 9.226 398.437 l h q 455.54 225.964 l /TT1 1 Tf 0 18 612 756 re /TT0 1 Tf 0 -1.2 TD Adipic acid, like most carboxylic acids, is a mild skin irritant. T* 0.801 0.801 0.801 rg endstream endobj 28 0 obj<>stream f h 604.312 469.171 l 7.688 555.858 l (CAS# 124-04-9: )Tj )Tj It is insoluble in water. 7.688 440.723 l 377.41 441.492 l 7.688 92.535 m ( )Tj 11.533 437.282 l 122.666 452.123 l 7.688 431.685 m 0 18 612 756 re 0.313 0.313 0.313 rg f 122.666 452.123 m (124-04-9)Tj 121.524 454.947 m f f 602.774 559.198 l 157.997 225.964 l 0.753 0.753 0.753 rg W* n 604.312 557.661 l 601.236 505.247 l 10.764 483.495 m 156.46 225.964 l h 603.543 441.492 l 9.226 154.181 l Q Succinic acid … 9.9358 0 0 9.9358 7.6884 216.1945 Tm EMC /T1_0 1 Tf 7.688 557.661 m 0000001794 00000 n ( )Tj 157.229 252.105 m h 8.6495 0 0 8.6495 51.6832 458.839 Tm /TT1 1 Tf f Topics discussed included chemical and physical properties, production, use, manufacturers and distributors, manufacturing processes, occupational exposure, and biological effects. h 378.179 454.178 l f W* n ( )Tj 600.467 482.726 l (Section 313)Tj f 306.769 237.881 l /TT1 1 Tf Vapor Density (Relative to Air): data unavailable, National Oceanic and Atmospheric Administration. /TT0 1 Tf f 122.666 465.577 m 604.312 457.354 l )Tj W* n -49.345 -1.556 Td T* 0 18 612 756 re 0.949 0.945 0.935 rg /TT1 1 Tf /Artifact <>BDC BT 600.467 435.529 l Adipic Acid Flinn Scientific, Inc. P.O. 0 -1.201 TD f )Tj 11.5327 0 0 11.5327 275.0348 740.5341 Tm ( )Tj f The industrial synthesis of adipic acid uses nitric acid oxidation of a mixture of cyclohexanone and cyclohexanol termed “KA oil” (ketone and alcohol-oil). 0 -1.201 TD 7.688 152.643 m h f 602.774 467.633 l Caus\ es eye irritation. ET Fine dusts may become potential Fine dust dispersal in the air near a heat or flame source is a potential dust explosion hazard Upper/lower flammability or explosive limit Not Available Vapor pressure (mmHg) 1 @ 159.5°C (320°F) Vapor density (air=1) 5.04 Relative density Not Available Solubility (ies) Soluble Partition coefficient: n-octanol/water Not Available Auto-ignition temperature 420°C (788°F) … (Extinguishing Media:)Tj h 604.312 440.723 l 604.312 486.57 m 600.467 400.743 l 603.543 252.105 m /TT0 1 Tf (Catalog Numbers:)Tj 0 0 0 rg 600.467 437.282 l 0.949 0.945 0.935 rg f 0 18 612 756 re 121.524 454.947 l q )Tj )Tj Q f 7.688 367.165 m 0 -1.201 TD Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in it to corrode or dissolve iron, steel, and aluminum parts and containers. 8.457 454.947 l Q 122.666 465.577 l )Tj f 9.226 506.785 l 602.774 485.033 l /T1_0 1 Tf /Artifact <>BDC h 305.231 251.336 l 0 18 612 756 re f 604.312 519.781 l f 602.774 64.856 l ( As in any fire, wear a self-contained breathing apparatus in pressure-d\ emand, MSHA/NIOSH )Tj 157.229 252.105 m 485.294 455.716 117.479 11.917 re In no )Tj 6.9196 0 0 6.9196 18 8.7488 Tm 11.533 706.034 l 10.764 155.718 m 11.533 148.388 l W* n 0 -1.2 TD COMPOSITION. 604.312 457.354 l EMC Q f ( This material does not contain any Class 2 Ozone depletors. Q (OSHA - Final PELs)Tj 0 0 0 rg q 363.873 464.809 l 0 -1.1 TD q ( )Tj T* 9.226 368.703 l 11.533 88.69 l f 9.226 682.2 593.548 26.141 re h 0000000143 00000 n /TT1 1 Tf 602.774 433.222 l EMC Q 0 -1 TD h h ( Has not been reported. (Not regulated as a hazardous material)Tj /TT1 1 Tf f Q 363.104 465.577 m 600.467 733.383 l (Section 9 - Physical and Chemical Properties )Tj 9.9358 0 0 9.9358 7.6884 125.5482 Tm /Artifact <>BDC q W* n 602.774 225.964 l T* (Skin:)Tj 377.41 454.947 l T* f 601.236 414.985 l f (adequate ventilation. /Artifact <>BDC 362.335 466.346 l f 0 0 0 rg (Hazard Class:)Tj (Shipping Name:)Tj 10.764 178.784 m Thermal hazard and reaction mechanism of the preparation of adipic acid through the oxidation with hydrogen peroxide Wei Jiang College of Safety Science and Engineering, Nanjing Tech University, Nanjing, China 484.526 454.947 l 0.375 -1.556 Td h (Chemical Name)Tj 604.312 758.755 l 10.7638 0 0 10.7638 7.6884 54.4007 Tm /TT0 1 Tf 0000057627 00000 n h 604.312 585.074 m /TT0 1 Tf Q ET 9.226 454.178 l 122.666 438.668 m (Adipic acid)Tj Adipic acid-1,6-13C2 | C6H10O4 | CID 16213372 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. W* n 378.179 442.261 l (Hazard Symbols:)Tj These reactions generate heat. 10.764 414.985 m 9.226 557.395 593.548 26.141 re 8.457 452.123 m 306.769 251.336 l 0 -1.199 TD 9.9358 0 0 9.9358 7.6884 757.4737 Tm 483.757 454.178 l f 600.467 583.033 l Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. /Artifact <>BDC f 9.226 394.844 l h 0 -1.201 TD h Finely dispersed particles form explosive mixtures in air. /Artifact <>BDC 601.236 170.685 m 0000031270 00000 n Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. ( )Tj 9.226 452.892 l 0.949 0.945 0.935 rg 0000052219 00000 n 602.774 172.222 l T* 9.9358 0 0 9.9358 7.6884 656.8288 Tm /TT1 1 Tf ( Not available. EMC 602.774 459.363 l /TT1 1 Tf 604.312 321.279 l h /Artifact <>BDC W* n 0 -1.2 TD h h (Section 5 - Fire Fighting Measures )Tj 11.533 422.271 l ( )Tj (ity resulting )Tj 0 0 0 rg ( Oral, rabbit: LD50 = >11 gm/kg; )Tj 601.236 324.354 l 0.753 0.753 0.753 rg ET W* n 604.312 633.998 m 0 Tc 0 Tw 0 Ts 100 Tz 0 Tr 6.9196 0 0 6.9196 18 781.7488 Tm Adipic Acid Flinn Scientific, Inc. P.O. 602.774 466.346 l f /Artifact <>BDC EMC q Minimize dust generation and accumulation. 603.543 452.123 l /Artifact <>BDC f Q (capable of creating a dust explosion. f /Artifact <>BDC 363.104 479.032 m 602.774 154.181 l ( )Tj W* n f 601.236 324.354 l /TT1 1 Tf EMC 0000000656 00000 n ADIPIC ACID is a carboxylic acid. 10.764 434.76 l 0000056815 00000 n 7.688 479.801 m 363.873 452.892 l f 454.771 225.195 l Adipic acid is a straight-chain aliphatic dicarboxylic acid, commonly used in the manufacturing of nylon-6,6 and plasticizers. 0 18 612 756 re 0.313 0.313 0.313 rg ( Keep away from sources of ignition. EMC (Adipic acid)Tj Biodegradability screening tests indicate that adipic acid is \ readily biodegradable. BT 0 18 612 756 re EPA has sufficient data to assess the hazards of and to make a determination on aggregate exposure to adipic acid, including exposure resulting from the exemption established by this action. 0 18 612 756 re (Personal Protective Equipment)Tj Avoid creating a dust cloud in handling, transfer and clean up. /Artifact <>BDC /TT0 1 Tf 7.688 604.781 m f (Section 2 - Composition, Information on Ingredients )Tj f 10.764 324.354 l 0 -1.201 TD ( no )Tj W* n /TT1 1 Tf 601.236 393.306 l 0 -1.199 TD endstream endobj 34 0 obj(https://fscimage.fishersci.com/msds/00390.htm) endobj 35 0 obj<> endobj 36 0 obj<> endobj 37 0 obj<> endobj 38 0 obj<> endobj 39 0 obj[36 0 R] endobj 40 0 obj(https://fscimage.fishersci.com/msds/00390.htm) endobj 41 0 obj(b�����Cu�|�!d�m) endobj 42 0 obj<> endobj 43 0 obj<> endobj 44 0 obj(0�#NJ��?~�����) endobj 45 0 obj<> endobj 46 0 obj<> endobj 47 0 obj<> endobj 48 0 obj<> endobj 49 0 obj<> endobj 50 0 obj<>stream 7.688 469.171 m f 9.9358 0 0 9.9358 7.6884 758.6306 Tm 0.753 0.753 0.753 rg 0 -1.1 TD 602.774 452.892 l Like most organic acids, adipic acid is a mild skin irritant and so exposure to it should be avoided. f 604.312 460.901 m f 123.434 478.263 l 604.312 479.801 m 0.457 0.449 0.431 rg f Q EMC 9.9358 0 0 9.9358 76.7038 347.1281 Tm f f Q 0 0 0 rg (guidelines for the classification determination are listed in 40 CFR Par\ ts 261.3. 6.9196 0 0 6.9196 18 8.7488 Tm 601.236 732.615 l 600.467 684.507 l 9.226 398.437 593.548 26.141 re q 604.312 604.781 l W* n 377.41 468.402 m h BT W* n )Tj Q 13.4548 0 0 13.4548 204.625 162.8311 Tm 0 0 0 rg f /Artifact <>BDC f h application/pdf Adipic acid (AA) 5-15% CAS-No 124-04-9 5-10%. h Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9351 Adipic acid is a white crystalline solid. q f 0 -1.201 TD 306.769 225.964 l (99 )Tj /TT1 1 Tf 121.897 412.527 l 0 -1.201 TD q 0 -1.201 TD 0.457 0.449 0.431 rg 0 18 612 756 re 121.524 441.492 l (event shall Fisher be liable for any claims, losses, or damages of any t\ hird party or for lost profits or any special, indirect,)Tj Adipic Acid Dihydrazide 1071-93-8 100% Section 3 – Hazards Identification Emergency Overview OSHA Hazards No known OSHA hazards HMIS Classification Health Hazard: 0 Flammability: 1 Physical hazards: 0 NFPA Rating Health Hazard: 0 Fire: 1 Reactivity Hazard: 0 Potential Health Effects Inhalation May be harmful if inhaled. Adipic Acid, Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com whether a discarded chemical is classified as a hazardous waste. 0.457 0.449 0.431 rg f 8.457 438.668 m f Q 9.226 412.527 l Dust may form explosive mixture with air (USCG, 1999). 157.229 225.195 m 604.312 181.859 m 604.312 367.165 l 455.54 225.964 l 485.294 455.716 l Facilities storing or\ utilizing this material should be equipped )Tj 0 0 0 rg Synonym: Hexanedioic acid; 1,4-Butane Dicarboxylic Acid Chemical Name: Adipic Acid … 0.801 0.801 0.801 rg 7.688 396.382 m 10.7638 0 0 10.7638 7.6884 402.992 Tm 7.688 396.899 l /TT1 1 Tf h q /Artifact <>BDC EMC ( Adipic acid is not expected to volatilize from dry soil surfaces based \ on its extrapolated vapor )Tj (Minnesota, Massachusetts. 0 18 612 756 re 0000001818 00000 n q f 601.236 178.784 m USA.gov. 121.524 454.947 l ( Causes eye irritation. 483.757 467.633 l 601.236 706.803 l 11.533 435.529 l 454.771 238.65 l 0 -1.201 TD ( )Tj EMC Q h Developmental and reproductive toxicity: Ingredients linked to developmental and reproductive toxicity, a broad class of health effects that range from infertility and reproductive organ cancers to birth defects and developmental delays in children. 601.236 683.738 l 0 -1.201 TD (oxygen. View information & documentation regarding Adipic acid, including CAS, MSDS & more. 157.997 237.881 l f 602.774 492.103 l 601.236 423.04 l 0 -1.201 TD Articles of Adipic acid are included as well. 0000057032 00000 n f )Tj ( Vacuum or sweep up material and place into a suitable disposal containe\ r. Clean up spills immediately, )Tj Q /TT1 1 Tf /Artifact <>BDC /TT0 1 Tf /TT0 1 Tf 0 0 0 rg ( May cause respiratory tract irritation. Adipic acid can be referred to as a di-acid since it has two carboxylate groups. EMC q Insoluble in water. /Artifact <>BDC (Ingestion:)Tj Adipic Acid (ADIPC) Safety Data Sheet According to the occupational safety and health (classification, labelling, and safety data sheet of hazardous chemicals) Regulation 2013 06/04/2017 EN (English US) 2/7 Name Product identifier % Classification according to the United Nations GHS (Rev. /WebCaptureBG BMC h 15.294 -0.001 Td /WebCaptureFN <>BDC (OSHA:)Tj Crystalline adipic acid should be stored … 377.41 454.947 m 0.949 0.945 0.935 rg /TT1 1 Tf (from its use. h Q /WebCaptureBG BMC 8.457 252.105 l ( ATMOSPHERIC FATE: According to a model of gas/particle partitioning of \ semivolatile organic compounds )Tj 121.897 452.892 l f h 604.312 152.643 l 11.533 325.123 l 601.236 347.42 l 9.226 442.261 l 0 -1.201 TD q Material Safety Data Sheet or SDS for Adipic acid 818650 from Merck for download or viewing in the browser. /TT0 1 Tf 0000057333 00000 n f 0.313 0.313 0.313 rg h 0 i 0 -1.201 TD 7.688 63.319 l f )Tj h h 7.688 729.539 l 7.688 633.998 m W* n Office of Response and Restoration, (Target Organs: )Tj q /TT0 1 Tf h Adipic Acid Dihydrazide 1071-93-8 100% Section 3 – Hazards Identification Emergency Overview OSHA Hazards No known OSHA hazards HMIS Classification Health Hazard: 0 Flammability: 1 Physical hazards: 0 NFPA Rating Health Hazard: 0 Fire: 1 Reactivity Hazard: 0 Potential Health Effects Inhalation … /TT0 1 Tf ( No chemicals are reportable under Section 313. 7.688 508.323 m 9.226 757.218 l 0 0 0 rg 0 18 612 756 re 377.41 468.402 m 0 18 612 756 re 363.104 452.123 m 7.688 479.801 m Revised on 06/05/2015 Page 1 of 6 Safety Data Sheet Adipic Acid, 99% 1. -6.946 -1.102 Td 601.236 583.801 l 0 18 612 756 re %%EOF, https://fscimage.fishersci.com/msds/00390.htm. EMC f f ( CAS# 124-04-9: 5000 lb final RQ; 2270 kg final RQ )Tj 600.467 482.951 l 7.688 144.544 m 362.335 478.263 l 0 18 612 756 re 602.774 239.419 l 0 -1.201 TD q /Artifact <>BDC ( AC102810000, AC102810010, AC102810025, AC102810030, AC102810050, AC1028\ 15000, )Tj ( )Tj f 454.003 251.336 l /TT0 1 Tf NO open flames. h 10.7638 0 0 10.7638 7.6884 358.2476 Tm 156.46 225.964 l ( In case of contact, flush skin with plenty of water. (that bioconcentration in aquatic organisms is low. 0 -1.201 TD 0 -1.2 TD 305.231 225.964 l 7.688 585.074 m f ( ACGIH says threshold limit value is based upon neurotoxicity. An 84% conversion of )Tj ET h (The information above is believed to be accurate and represents the best\ information currently available to us. h 10.764 706.803 m ( 2.0 g/100g @ 25\260C )Tj h /TT0 1 Tf 602.774 708.341 l 0.457 0.449 0.431 rg 9.9358 0 0 9.9358 7.6884 44.3229 Tm 7.688 490.565 l ( )Tj 0.313 0.313 0.313 rg (Not available. TCC’s Adipic Acid is a mildly toxic, white, crystalline compound. The main risk in handling adipic acid is the danger of explosion. 9.226 424.444 l 0 -1.099 TD 10.764 558.933 l 122.292 455.716 l f 601.236 66.394 l 121.897 451.354 l ( CAS# 124-04-9 is listed on the Canadian Ingredient Disclosure List.\ )Tj 376.641 454.178 l )Tj 157.229 238.65 l h Adipic acid is a white crystalline solid. h 10.764 558.933 m 363.104 479.032 m W* n (Clean Air Act:)Tj 7.688 633.998 m 601.236 399.975 l Neutralization between an acid and a base produces water plus a salt. (Respiratory system, gastrointestinal system, eyes, nervous system, skin.\ )Tj )Tj 0.949 0.945 0.935 rg 7.688 758.755 m Adipic Acid Dihydrazide has been used as a chemical additive in a variety of cosmetic products. 601.236 630.922 m 0 18 612 756 re 9.9358 0 0 9.9358 7.6884 350.308 Tm ( CAS# 124-04-9 can be found on the following state right to know lis\ ts: California, New Jersey, Pennsylvania, )Tj 10.764 66.394 l 11.533 630.153 l 0.753 0.753 0.753 rg 0 18 612 756 re f f /TT1 1 Tf 9.226 731.077 l 0 -1.199 TD Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. 10.764 438.051 m h ( )Tj 0 -1.2 TD q 7.688 441.126 m 602.774 606.319 l 8.457 454.947 m 454.003 251.336 l 601.236 414.985 l W* n 0.949 0.945 0.935 rg 602.774 506.785 l 0 -1.201 TD f 363.104 452.123 l 10.764 583.801 m h ( )Tj EMC 157.229 238.65 m 484.526 468.402 l The available safety test data were insufficient to judge the safety of use of Adipic Acid Dihydrazide … 9.226 433.222 l 10.764 399.975 l W* n 0 18 612 756 re View information & documentation regarding Adipic acid, including CAS, MSDS & more. 10.764 706.803 m (NIOSH/MSHA or European Standard EN 149 approved respirator if exposure l\ imits are exceeded or if irritation or )Tj T* 363.873 478.263 l 13.4548 0 0 13.4548 186.5754 422.098 Tm 0 -1.201 TD 602.774 606.319 l ( )Tj h (https://fscimage.fishersci.com/msds/00390.htm)Tj Q This section provides a listing of alternate names for this chemical, f 306 225.195 l (Engineering Controls:)Tj f (none listed )Tj 120.755 454.178 l 9.9358 0 0 9.9358 7.6884 758.6238 Tm )Tj 9.226 585.339 l The primary hazard is the threat to the environment. (breathing dust. ( Fair Lawn, NJ 07410 )Tj h Avoid )Tj W* n (with an eyewash facility and a safety shower. 9.226 452.892 l )Tj 0000001140 00000 n f ( )Tj 9.9358 0 0 9.9358 7.6884 144.4111 Tm 601.236 370.241 l Chemical waste generators must also consult local, regional, and national hazardous waste regulations. h 7.688 508.323 m 8.457 452.123 m Topics discussed included chemical and physical properties, production, use, manufacturers and distributors, manufacturing processes, occupational exposure, and biological effects. 363.873 466.346 l h /TT0 1 Tf /TT0 1 Tf 17.152 0 Td f ET /Artifact <>BDC Hand protection: Protective gloves 602.774 439.588 l 9.226 731.077 593.548 26.141 re 9.226 348.957 l Adipic acid is present in some plants and is a chemical in tobacco and tobacco smoke. 483.757 454.178 l Q Sigma-Aldrich offers a number of Adipic acid products. /TT1 1 Tf f f 377.41 468.402 m /TT0 1 Tf (330 deg C )Tj 377.41 454.947 m 604.312 252.874 l Q h h Q 0 18 612 756 re h q h 156.46 251.336 l f h Q h )Tj f 10.764 583.801 m f /TT1 1 Tf W* n (1.360 g/cm @ 20/4\260C )Tj 0.753 0.753 0.753 rg Minimum explosible concentration in air (dust): 10-15 mg/L. )Tj /T1_0 1 Tf 602.774 424.578 l q f 604.312 709.878 l /Artifact <>BDC Closed system, dust explosion-proof electrical equipment and lighting. /Artifact <>BDC 10.764 393.306 m /TT1 1 Tf f 7.688 486.57 m Section 3: Composition / Information on Ingredients Adipic Acid (124-04-9), 100% Section 4: First Aid Measures Always seek professional medical attention after first aid measures are provided. 485.294 454.178 l (Upper:)Tj /TT1 1 Tf 0.457 0.449 0.431 rg 601.236 170.685 l The result is an odorless white crystalline powder with a slightly acidic taste. 363.104 452.123 l ( )Tj f 4, 2011) Adipic Acid … (Warning! EMC (Handling:)Tj 0.949 0.945 0.935 rg f 602.774 455.716 l (Skin:)Tj 0 18 612 756 re h 0 -1.199 TD /TT1 1 Tf /TT1 1 Tf 0.949 0.945 0.935 rg f 9.226 413.448 593.548 26.141 re 601.236 493.64 l /TT0 1 Tf 10.764 147.619 l Adipic Acid (ADIPC) Safety Data Sheet According to the occupational safety and health (classification, labelling, and safety data sheet of hazardous chemicals) Regulation 2013 06/04/2017 EN (English US) 2/7 Name Product identifier % Classification according to the United Nations GHS (Rev. (For CHEMTREC assistance, call:)Tj 602.774 424.578 l 0 -1.199 TD h f /TT1 1 Tf q W* n 0 -1.2 TD 9.226 180.321 l f Information on potential occupational hazards from exposure to adipic-acid (124049) was reviewed. h )Tj h 454.003 225.964 l 603.543 441.492 l ( 5.04 \(air=1\) )Tj f 602.774 90.997 l 601.236 516.706 l 601.236 732.615 l f 9.995 0 0 9.995 432.3956 691.0602 Tm 13.4548 0 0 13.4548 181.9201 614.9696 Tm 11.533 178.015 l The C6 straight-chain dicarboxylic acid is slightly soluble in water and soluble in alcohol and acetone. 0.801 0.801 0.801 rg 8.457 411.758 l 600.467 608.626 l f 7.688 252.874 m 378.179 442.261 l 121.897 464.809 l 603.543 238.65 l Adipic Acid, Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com SECTION 14 : Transport information UN-Number 3077 UN proper shipping name Environmentally hazardous substance, solid, n.o.s. f /Artifact <>BDC ( Use proper personal protective equipment as indicated in Section 8. 454.771 252.105 m ( )Tj 0000004796 00000 n 123.434 466.346 l 7.688 586.877 m ( Ingestion of large amounts may cause gastrointestinal irritation. h EMC 600.467 482.726 l 10.764 370.241 m h (adipic acid's carbon content to carbon dioxide was observed after 30 day\ s aerobic incubation in soil biometer flasks at )Tj ( 6/17/1999 )Tj f 602.774 368.703 l ( )Tj Q Production of adipic-acid was 1.8 … q (Eye:)Tj f h ( )Tj CAS 124-04-9, pH 2.7 (24.9 g/l, H₂O, 25 °C). (Section 3 - Hazards Identification )Tj 8.457 425.213 m 11.533 346.651 l uuid:94b24c6e-a8b6-4a48-aeea-d0ec52e1cf59 /TT0 1 Tf 0 -1.201 TD EMC )Tj )Tj (Packing Group:)Tj f )Tj (Molecular Formula:)Tj 0000056699 00000 n 0 i EMC ( No data available. ( 800-424-9300 )Tj 9.226 518.243 l )Tj f 0.753 0.753 0.753 rg Avoid generat\ ing dusty conditions. 8.457 252.105 l 10.7638 0 0 10.7638 7.6884 720.6214 Tm 11.533 169.916 l h 603.543 411.758 l (Section 6 - Accidental Release Measures )Tj f /TT1 1 Tf However, we make)Tj (Hazardous Polymerization:)Tj ( 6/06/2006 )Tj T* h 0 -1.201 TD 10.764 89.459 m 122.666 411.758 l The nylon, which … 11.533 581.229 l 10.764 482.182 m Utilizing principles of green chemistry, a new method of synthesis has been developed, which involves oxidizing cyclohexene with hydrogen peroxide via a tungsten catalyst and a phase transfer catalyst to produce adipic acid. h 455.54 239.419 l 122.666 438.668 l h /Artifact <>BDC 11.533 515.937 l ( )Tj Additionally, waste generators must )Tj h 8.457 411.758 m 156.46 239.419 l Hazards identified by OECD/ICCA high production volume chemicals program in 2004: "Adipic acid was orally administered to humans to investigate compound excretion. 604.312 224.426 l f 306.769 239.419 147.234 11.917 re f 600.467 392.537 l ( None of the chemicals in this product are listed as Toxic Pollutant\ s under the CWA. h 601.236 483.495 l q /TT0 1 Tf ( )Tj 485.294 442.261 l 600.467 392.537 l 11.533 581.229 l Remove contaminate\ d clothing and shoes. 8.457 454.947 m 600.467 559.702 l f 7.688 680.662 m 0 18 612 756 re W* n h /TT0 1 Tf EMC q 0 -1.2 TD 601.236 583.801 m 602.774 322.817 l Associated with adipic acid 818650 from Merck for download or viewing in the production polyurethanes. 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